Download the utility file.exe from
http://www.vowles-home.demon.co.uk/utils/file.zip
Now run the command
file pidgin-2.6.6.exe
pidgin-2.6.6.exe, DOS/Win, i386 32bit executable, GUI, PE format
file c:\wordpad.exe
c:\wordpad.exe, DOS/Win, x86-64 64bit executable, GUI, PE format
file c:\TeraCopyExt64.dll
c:\TeraCopyExt64.dll, DOS/Win, x86-64 64bit executable, dll, GUI, PE format
file c:\TeraCopyExt.dll
c:\TeraCopyExt.dll, DOS/Win, i386 32bit executable, GUI, PE Modifed